You won't ovulate on the five days you're taking Clomid pills. However, with your first dose, Clomid begins a chain reaction that will eventually lead to ovulation. Clomid (clomiphene citrate) is used in women who do not ovulate (produce eggs) regularly each month leading to infertility. Clomid stimulates ova (eggs) to. I was on provera first to have a period. On day 7 I started my first cycle of clomid, I have 2 more days left when do you start to ovulate and when.